Alessandro Volta
Alessandro Volta was a physicist, chemist and a pioneer of electrical
science. He is most famous for his invention of the electric battery.
In brief he:
• Invented the first electric battery – which people then called the
“voltaic pile” – in 1800. Using his invention, scientists were able to
produce steady flows of electric current for the first time, unleashing a
wave of new discoveries and technologies.
• Was the first person to isolate methane.
• Discovered methane mixed with air could be exploded using an
electric spark: this is the basis of the internal combustion engine.
• Discovered “contact electricity” resulting from contact between different metals.
• Recognized two types of electric conduction.
• Wrote the first electromotive series. This showed, from highest to
lowest, the voltages that different metals can produce in a battery. (We
now talk of standard electrode potentials, meaning roughly the same
thing.)
• Discovered that electric potential in a capacitor is directly proportional to electric charge.
In recognition of Alessandro Volta’s contributions to electrical science, the unit of electric potential is called the volt.
Early Life and Education
Alessandro Volta was born in Como, Lombardy, Italy, on February 18,
1745. His family was part of the nobility, but not wealthy. Until the
age of four, he showed no signs of talking, and his family feared he was
not very intelligent or possibly dumb. Fortunately, their fears were
misplaced.
When he was seven, his father died leaving unpaid debts. The young
Alessandro Volta was educated at home by his uncle until he was twelve
years old. He then started studies at a Jesuit boarding school. The
Jesuit school charged no fees, but pressurized him to become a priest.
His family did not want this, and withdrew him from the school after
four years. Volta then studied at the Benzi Seminary until reaching
eighteen years of age.
Volta’s family wanted him to become a lawyer. Volta had his own
ideas! He was interested in the world around him; he wanted to be a
scientist.
Although as a child he had been slow to speak Italian, Volta now
seemed to have a special talent for languages. Before he left school, he
had learned Latin, French, English and German. His language talents
helped him in later life, when he traveled around Europe, discussing his
work with scientists in Europe’s centers of science.
Aged 18, Volta was bold enough to begin an exchange of letters about
electricity with two leading physicists: Jean-Antoine Nollet in Paris,
and Giambatista Beccaria in Turin. Beccaria did not like some of Volta’s
ideas and encouraged him to learn more by doing experiments.
When he wrote his first dissertation, Volta addressed it and dedicated it to Beccar
Volta’s Career Timeline Before the Battery
Amateur Scientist, Inventor, Teacher and Physics Professor
1765 – Volta had reached 20 years of age. His wealthy friend Giulio
Cesare Gattoni had built a physics laboratory in his home. For several
years he kindly allowed Volta to do experiments in this laboratory.
1765 – Volta wrote his first scientific paper, which he addressed to
Giambatista Beccaria, about static electricity generated by rubbing
different substances together – i.e. triboelectricity.
1769 – Volta published a dissertation titled On the Attractive Force of the Electric Fire, and on the Phenomena Dependent On It,
which he sent to Beccaria. He discussed his ideas on the causes of
electrical attraction and repulsion and compared these with gravity. He
set out his position that, like gravity, static electricity involved
action at a distance. The main scientists influencing his thinking were
Isaac Newton, Roger Boscovich, Benjamin Franklin and Giambatista
Beccaria himself.
1771 – Volta read Joseph Priestley’s 1767 review of scientific
research on electricity. He learned that some discoveries he had made
recently had already been made by others.
1774 – Volta began work overseeing schools in Como. He said that
teaching in Como’s classrooms should be modernized. He wanted the
children to spend more time learning science and modern languages.
1775 – Volta began teaching experimental physics in Como’s public grammar school, where he worked until 1778.
1775 – Volta wrote a letter to Joseph Priestley. He explained how he
had invented a device which was a source of static electricity: the
electricity could be transferred to other objects. We call this device
the electrophorus. Volta wanted to know if the device was a new
invention. Priestly told him Johann Wilcke had invented such a device
in 1762, but Volta had invented it independently. Priestley encouraged
Volta to keep up his interesting research work.
1776 – Aged 31, Volta was the first person to isolate methane gas. He
discovered that a methane-air mixture could be exploded in a closed
container with an electric spark. In the future, an electrically started
chemical reaction like this would be the basis of the internal
combustion engine.
1776 – Volta suggested that the sparking apparatus he used to explode
methane could also be used to send an electric signal along a wire from
Como to the city of Milan.
1777 – Volta invented a much better eudiometer than any that had gone
before. A eudiometer tests how much oxygen is present in air to
determine how good for breathing it is. Volta’s eudiometer was superior
to others because it used hydrogen as the gas reacting with oxygen,
giving a clean, reliable reaction. The reaction was also cleanly started
using an electric spark. The eudiometer worked on the basis that the
decrease in volume of hydrogen after sparking was proportional to the
amount of oxygen present in air.
1777 – Volta set out on a scientific journey to Switzerland and
France. He met other scientists and showed them his innovations in
electrical equipment. He also traveled so that his name would become
better known outside Italy.
1778 – Volta was appointed to the Chair of Experimental Physics at
the University of Pavia, about 55 miles (85 km) from Como, a position he
would hold for over 40 years.
1778 – Volta discovered that the electrical potential (we now often call this the voltage) in a capacitor is directly proportional to electrical charge.
1781 to 1782 – Volta traveled around most of Europe’s major
scientific centers, including the French Academy in Paris, demonstrating
his electrical equipment and inventions to eminent people such as
Antoine Lavoisier and Benjamin Franklin. Volta was beginning to become
well-known outside Italy.
1782 – Volta wrote about the condenser he had constructed (today we
would call it a capacitor) to collect and store electric charge, and how
he had used it to study a variety of electrical phenomena.
1788 – Volta built increasingly sensitive electroscopes to detect and measure the effects of electric charge.
1790 – Volta carried out experiments on the behavior of gases. He
found an accurate value for air’s increasing volume with rising
temperature.
1791 – Recognizing that he had become one of Europe’s foremost
electrical scientists, Volta was elected to be a Fellow of the Royal
Society of London.
1794 – At the age of 50, Volta was awarded the Royal Society’s top
prize – the Copley Medal – for his contributions to scientific
understanding of electricity.
Invention of the Electric Battery
A Feud over Frogs’ Legs led to the Battery
Volta did not set out to invent the battery. His experiments in this
area were actually performed to show the claims of another scientist
were wrong. That scientist was another Italian, Luigi Galvan
Galvani was a professor of anatomy. In the late 1780s he noticed that a
spark of static electricity carried by a metal scalpel touching the
nerves of a dead frog while the legs lay on metal caused the legs to
move.
This was an amazing discovery: animal movement was based on electricity in some way.
In 1817, this led to Mary Shelley writing Frankenstein. In
this novel, a creature made from a monstrous mixture of body parts from
dead people is brought to life by Doctor Frankenstein using electricity
from a lightning storm.
In 1791, Galvani announced his discovery of animal electricity.
He believed that animals generated electricity in their bodies and that
a fluid within animals’ nerves carried electricity to muscles, causing
movement. He believed that electricity from an outside source released a
flow of electrical fluid from the nerves, causing the muscles to jump.
He also believed that animals such as electric eels could build up
extra amounts of this fluid and use it to deliver electric shocks.
Galvani concluded that animal electricity was similar to static electricity, but it was different and was a unique property of living things.
Enter Volta
Volta studied Galvani’s phenomenon.
In 1792, Volta said that the “animal” part of Galvani’s animal electricity was not needed. Animals merely responded to normal electricity. There was no difference between animal electricity and electricity.
Volta performed various experiments on frogs’ legs. He found the key to getting them to move was contact with two different metals. Contact with pieces of the same metal did nothing.
Then, moving away from frogs’ legs, in 1794, Volta did experiments to
measure the electrical effect of bringing different pairs of metals
into contact. He listed the metals in order of what he called their
electromotive force.
This was the first time anyone had listed electrode potentials. It was the first electrochemical series.
In modern language, we would say that the farther apart the
substances on this list are, the greater the voltage they will produce
when brought into contact or used as the electrodes in electric cells
and batteries. For example, a zinc-graphite cell will produce a greater
voltage than a zinc-lead cell.
By 1797, Volta had completely proved his “contact theory” of electricity.
He now knew that the key to producing what today we call a voltage
was two metals connected by by something moist, like frogs’ legs. The
moist connection between the metals did NOT have to be an animal.
Connecting the metals by placing them in a cup of dilute acid was a very
effective way of producing electricity.
He formally split electrical conductors into those of the first kind: these were metals, graphite and pure charcoal; and the second kind:
these were substances we would now call electrolytes, such as salt
water or dilute acids. An electric current would result when a circuit
was built using two conductors of the first kind combined with one of
the second kind
Alternatively, connecting the metals with paper soaked in dilute acid or salt water also worked.
Volta said that in Galvani’s work, the frogs’ legs had served two functions:
- They conducted electricity as conductors of the second kind.
- They acted as a very sensitive electroscope. (An electroscope is a device used to detect electricity.)
Volta found that by connecting up more and more pairs of metals
connected with moist card, he could produce ever higher voltages,
leading to significant electrical currents.
And so the electrical battery was born.
Volta used alternating zinc and silver discs linked by card or cloth soaked in salt water.
In 1800, Volta described his results in a letter to Joseph Banks, at the Royal Society in London.
Banks showed the letter to other scientists, and arranged for Volta’s
description of his discovery to be read out at a meeting of the Society
and published.
Volta’s Battery Unleashed a Wave of New Scientific Discoveries
The battery that Volta had invented gave chemists a very powerful new method to study substances.
The beauty of Volta’s device was that almost anyone could make one –
silver and copper coins were available to many people, as were other
metals such as iron, tin and zinc.
Within weeks of Volta’s invention of the battery, William Nicholson
and Anthony Carlisle built and used a battery to decompose water into
hydrogen and oxygen.
Within just six years, Humphry Davy had built a powerful battery.
With it, he isolated new chemical elements, and deduced that chemical
bonds were electrical in nature.
discoveries of the new elements barium, calcium, lithium, magnesium,
potassium, sodium, and strontium, were all made possible by Volta’s
invention of the battery.
By 1820, courtesy of Volta’s batteries, Hans Christian Oersted was
investigating the relationship between electricity and magnetism.
By 1821, Michael Faraday had produced an electric motor.
Volta’s battery produced a steady source of electric current for the
first time ever. All electrical devices depend on electric current.
Without Volta’s invention, there could be no modern technology. Volta’s
battery was an absolutely crucial invention in the development of our
technology based civilization.
The End
In 1819, at the age of 74, Volta decided it was time to hang up his
capacitors, his voltaic piles, his electrophorus, and his administrative
work at the university. He retired to a country house close to his home
town of Como, where he could spend more time with his wife, Maria
Teresa. They had three sons, Zanino, Faminio and Luigi.
Volta lived in Como until his death, aged 82, on March 5, 1827.
In 1881, scientists decided that the unit of electric potential would be called the volt to recognize Volta’s great contributions to electrical science.
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